Solvent effects on Grubbs' pre-catalyst initiation rates.
نویسندگان
چکیده
Initiation rates for Grubbs and Grubbs-Hoveyda second generation pre-catalysts have been measured accurately in a range of solvents. Solvatochromic fitting reveals different dependencies on key solvent parameters for the two pre-catalysts, consistent with different mechanisms by which the Grubbs and Grubbs-Hoveyda pre-catalysts initiate.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 42 12 شماره
صفحات -
تاریخ انتشار 2013